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991.
992.
This paper reports on the application of conventional models (the displacement model and the elongation model) and the four-parameter model in detecting the local molecular structure of a coordination complex. By diagonalizing the complete energy matrices, the EPR parameters and optical spectra as well as the local distortion structure for V3+ ion in the Al2O3 : V3+ system have been studied using the three models. The four-parameter model is shown to provide a significant improvement over the conventional models. Based on these calculations, it was found that when V3+ is doped in Al2O3, the distance between upper and lower ligand oxygen plane increases by 0.16097 Å and the shifts of O2? ions in the upper and lower ligand oxygen planes expand by 0.07076 Å and 0.004066 Å, respectively. To understand the detailed physical and chemical properties of the doped Al2O3, the contributions of the spin-orbit coupling to the zero-field splitting for V3+ ion are investigated. 相似文献
993.
Chris J.G. Bakker Hendrik de Leeuw Gerrit H. van de Maat Jetse S. van Gorp Job G. Bouwman Peter R. Seevinck 《Magnetic resonance imaging》2013
Lack of spatial accuracy is a recognized problem in magnetic resonance imaging (MRI) which severely detracts from its value as a stand-alone modality for applications that put high demands on geometric fidelity, such as radiotherapy treatment planning and stereotactic neurosurgery. In this paper, we illustrate the potential and discuss the limitations of spectroscopic imaging as a tool for generating purely phase-encoded MR images and parameter maps that preserve the geometry of an object and allow localization of object features in world coordinates. 相似文献
994.
Abstract The effect of pressure on the two polymorphs of [CO(NH3)5NO2]I2 (phase I-orthorhombic, S.G. Pnma; phase II-monoclinic, S.G. C2/m) was studied by X-ray powder diffraction in a diamond anvil cell (DAC). In the presence of the ethanol-methanol-water mixture used as a pressure-transmitting liquid polymorph I was shown to undergo a phase transition at pressures between 0.45 GPa and 0.65 GPa. The diffraction pattern of the high-pressure phase (phase III) could be indexed as tetragonal with lattice parameters similar to those, which were previously reported for polymorph II in a 'pseudotetragonal setting'. The lattice distortions of phases II and III were studied at pressures up to 3.2 GPa and 3.7 GPa, correspondingly, and were shown to be very similar. Phases II and III were supposed to be very closely related. If poly(chlortrifluorethylen)-oil was used as a pressure-transmitting medium, no phase transitions were observed in phase I of [CO(NH3)5NO2I2 at least up to 1.8 GPa (the point when poly(chlortrifluorethylen)-oil becomes solid), and the anisotropy of lattice distortion could be measured. 相似文献
995.
面向目标的定向声辐射是指利用声源特性和阵列信号处理技术,将声波传送至目标方向或区域的声场控制方法。本文介绍了定向声辐射技术的原理和进展,重点阐述了普通扬声器阵列和参量阵扬声器这两种声源形式的理论、算法和应用研究。其中,针对扬声器阵列,主要分析了基于声能量对比度控制的声聚焦技术;针对参量阵扬声器,综述了利用非线性效应产生高指向性可听声的计算方法、信号预处理和应用等进展。面向目标的定向声辐射技术的研究对实现智能声场控制有着重要意义。 相似文献
996.
997.
Camera calibration is a fundamental and important step in many machine vision applications. For some practical situations, computing camera parameters from merely a single image is becoming increasingly feasible and significant. However, the existing single view based calibration methods have various disadvantages such as ignoring lens distortion, requiring some prior knowledge or special calibration environment, and so on. To address these issues, we propose a line-based camera calibration method with lens distortion correction from a single image using three squares with unknown length. Initially, the radial distortion coefficients are obtained through a non-linear optimization process which is isolated from the pin-hole model calibration, and the detected distorted lines of all the squares are corrected simultaneously. Subsequently, the corresponding lines used for homography estimation are normalized to avoid the specific unstable case, and the intrinsic parameters are calculated from the sufficient restrictions provided by vectors of homography matrix. To evaluate the performance of the proposed method, both simulative and real experiments have been carried out and the results show that the proposed method is robust under general conditions and it achieves comparable measurement accuracy in contrast with the traditional multiple view based calibration method using 2D chessboard target. 相似文献
998.
运用功率谱反演法对斜程传输大气湍流扰动相位屏进行了数值模拟。通过建立激光束初始畸变相位模型,从波前峰谷值和波前功率谱密度函数两个方面,对激光束通过大气湍流后的相位特性进行了研究,重点分析了湍流传输距离和天顶角对激光束波前相位分布的影响。研究结果表明:激光束在湍流大气斜程传输后,其波前相位会发生明显畸变,且空间高频相位较低频相位所占比例明显增加;通过湍流后的波前相位与传输距离及天顶角密切相关,传输距离越长,天顶角越大,相位畸变程度越大,高频相位所占比例越多。 相似文献
999.
柑橘皮黄酮提取工艺及抑制亚硝化反应 总被引:1,自引:0,他引:1
研究柑橘皮中黄酮类化合物的提取工艺及黄酮类物质对亚硝化反应的抑制能力.通过单因素及L9(34)正交试验,探讨最佳提取工艺条件及相关工艺参数,并采用分光光度法测定黄酮提取液对亚硝胺抑制能力和对亚硝酸盐清除能力.结果表明,柑橘皮中黄酮类化合物的最佳提取工艺条件为乙醇体积分数60%、料液比1∶40(g/mL)、提取时间50min、提取温度70℃.柑橘皮中黄酮类化合物提取液对亚硝胺合成的最大阻断率为75.8%,对亚硝酸钠的最大清除率为85%.柑橘皮中黄酮类化合物提取液对亚硝化反应的抑制能力较强,且最佳工艺操作简单快捷,适用于工业化大批量提取柑橘皮中黄酮类化合物. 相似文献
1000.
X-ray absorption spectra (XAS) at Mn K-edge and Fe K-edge in LaMnl-xFexO3 show that with the increase of Fe substitution the chemical valence of Mn4+ decreases, while the chemical valence of Fe3+ remains unchanged. Structural distortions, such as the rotating and tilting for oxygen octahedron in the unit cell vary with iron content. A phase transition occurs at the Fe content values of 0.2~0.3. The evolutions of rotation and tilting angle of FeO6/MnO6 octahedral may be the vital factors to the structure and magnetism. We believe that the spin configuration of Fe3+ may vary from the intermediate spin t2g4eg1 (S = 3/2) to the higher spin t2g3eg2 (S = 5/2) near the phase transition. 相似文献